はじめに
Selecting the right colorant for engineering plastics is a complex process. While many organic pigments, inorganic pigments, and solvent dyes work well for general thermoplastics, high-performance materials like Nylon (Polyamide) have strict requirements.
Below, we explore the five critical performance characteristics colorants must possess for successful Nylon injection molding[^1].
1. Heat Resistance and Lightfastness
The processing temperature of the resin dictates the stability requirements for the colorant. As shown in the table below, Polyamide (Nylon) requires some of the highest processing temperatures among engineering plastics[^2].
Processing Temperatures and Colorant Requirements by Resin Type
| Resin Type | Processing Temp (℃) | Key Colorant Requirements |
|---|---|---|
| Polyamide (Nylon) | 270 - 290 | Heat resistance, Water-free, Good dispersion |
| Polyester | 270 - 290 | Heat resistance, Non-migrating, Neutral pH |
| ABS | 230 - 310 | Heat resistance, Good dispersion |
| Polypropylene | 230 - 280 | Heat resistance, Good dispersion |
| Polyurethane | 210 - 270 | Lightfastness, Acid/Reduction resistance |
| PMMA | 200 - 230 | Fastness, Heat resistance, Non-migrating |
| PVC | 180 - 250 | Good dispersion, Acid resistance |
| Polystyrene | 180 - 240 | Fastness, Good solubility |
| Polycarbonate | 150 - 200 | Heat resistance, Water-free, Good dispersion |
| 高密度ポリエチレン | 160 - 230 | High thermal stability, Non-migrating |
| LDPE | 150 - 220 | Excellent fastness, Non-migrating |
> 注: Due to the high processing temperatures of Polyamide, colorants must exhibit exceptional thermal stability. Many organic pigments can negatively affect the properties of the Nylon melt, limiting the selection to specific high-performance pigments with good lightfastness.

2. Chemical Stability
There must be no chemical reaction between the colorant and the resin, nor should the colorant promote resin decomposition.
Polyamide resins (PA) are highly active. In their molten state, they exhibit reducing properties, which can easily cause colorants to shift in hue or degrade. Therefore, the choice of colorants for Nylon is limited to those with high chemical inertness.
3. Migration Resistance
Migration refers to the movement of the colorant within the polymer or to the surface. There are three main types:
- Solvent Extraction: Leaching of color in water or organic solvents.
- Contact Migration: Staining of adjacent objects or packaging.
- Blooming (Surface Frosting): The colorant has high solubility at high heat but low solubility at room temperature, causing it to migrate to the surface as the part cools.
Inorganic vs. Organic: Generally, inorganic pigments are heterogeneously dispersed in polymers and rarely bloom. In contrast, organic pigments have varying degrees of solubility in polymers, making them more prone to migration issues.

4. Tinting Strength
Tinting strength determines the dosage of colorant required to achieve the target color.
- Particle Size: Generally, tinting strength increases as the pigment particle size decreases.
- Organic vs. Inorganic: Organic pigments[^3] typically have higher tinting strength than inorganic pigments.
- Mixing: Tinting strength can be significantly improved when colored pigments are used in combination with white pigments.
5. Dispersion
For optimal coloring results, the colorant must be uniformly dispersed in the polymer as microscopic particles.
Pigments often contain many aggregated particles. To achieve the desired quality, high shear force is required during the compounding process to break down large aggregates into smaller clusters. Poor dispersion leads to color streaks and weak points in the final part.

[^1]: Explore this resource to gain insights into optimal techniques and tips for successful Nylon injection molding. [^2]: Explore this resource to gain in-depth knowledge about engineering plastics, their properties, and applications in various industries. [^3]: Organic pigments can offer vibrant colors and higher tinting strength, making them valuable for specific applications.
著者について

アレックス・ユー
アイデアル・プロ・マニュファクチャリング
アレックスはIdeal Proの共同創業者ですが、重要なプロジェクトの監督や技術チームの指揮をとっていないときは、長距離サイクリングを楽しんだり、街で一番おいしいコーヒーを探し回ったり、次の旅の計画を立てたりしている姿を見かけるでしょう。 国際貿易の営業やプロジェクト管理に20年以上の経験を持つ彼は、厳しい納期や厄介な技術的課題など、ありとあらゆる状況を経験してきました。彼は、素晴らしい仕事は十分な休息と一杯の美味しいコーヒーから生まれると信じており、その好奇心と細部へのこだわりを、手掛けるすべてのプロジェクトに注ぎ込んでいます。 オフィスにいないときは、たいてい屋外で、新しい場所を探索したり、皆と共有できるエピソードを集めたりしています。.




